Homogeneous Catalysis ?>

Homogeneous Catalysis


Valorization of CO2: Preparation of 2-Oxazolidinones by Metal-Ligand Cooperative Catalysis with SCS Indenediide Pd Complexes
P. Brunel, J. Monot, C. E. Kefalidis, L. Maron, B. Martin-Vaca, D. Bourissou
ACS Catal., 2016, 7, 2652 – 2660.

Rational Development of Catalytic Au(I)/Au(III) Arylation Involving Mild Oxidative Addition of Aryl Halides
A. Zeineddine, L. Estévez, S. Mallet-Ladeira, K. Miqueu, A. Amgoune, D. Bourissou
Nature Commun., 2017, 8, 565 – 573.

Amino Groups Backbone-substituted NHC Ligands in Ruthenium-Catalyzed Olefin Metathesis of Challenging Substrates
V. César, Y. Zhang, W. Kośnik, A. Zieliński, A. A. Rajkiewicz, M. Ruamps, S. Bastin, N. Lugan, G. Lavigne, K. Grela
Chem. Eur. J., 2017, 23, 1950 – 1955.

Buttressing effect as key design principle towards highly efficient palladium/N-heterocyclic carbene Buchwald-Hartwig amination catalysts
Y. Zhang, G. Storch, G. Lavigne, N. Lugan, V. César
Chem. Eur. J., 2017, 23, 13792 – 13801.

Homogeneous iron catalysis – Highlights on the increasing impact of a non-noble metal
C. Darcel, J.-B. Sortais
Isr. J. Chem., 2017, 57, 1069.

Transfer Hydrogenation of Carbonyl Derivatives Catalyzed by an Inexpensive Phosphine-Free Manganese Precatalyst
A. Bruneau-Voisine, D. Wang, V. Dorcet, T. Roisnel, C. Darcel, J.-B. Sortais
Org. Lett., 2017, 19, 3656 – 3659.

The cyclooctadiene ligand in [IrCl(COD)]2 is hydrogenated under transfer hydrogenation conditions: A study in the presence of PPh3 and a strong base in isopropanol
S. M. W. Rahaman, J.-C. Daran, E. Manoury, R. Poli
J. Organometal. Chem., 2017, 829, 14 – 21.

Catalytic redox isomerization of allylic alcohols with rhodium and iridium complexes with ferrocene phosphine-thioether ligands
E. M. Titova, S. M. W. Rahaman, E. S. Shubina, R. Poli, N. V. Belkova, E. Manoury
J. Mol. Catal. A, 2017, 426, 376 – 380.

Rhodium-catalyzed aqueous biphasic hydrogenation of alkenes with amphiphilic phosphine-containing core-shell polymers
A. Joumaa, S. Chen, S. Vincendeau, F. Gayet, R. Poli, E. Manoury
Mol. Cat., 2017, 438, 267 – 271.

Catalyzed Chain Transfer in Vinyl Acetate Polymerization mediated by 9-Oxyphenalenone Cobalt(II) complexes
E. V. Bellan, L. Thevenin, F. Gayet, C. Fliedel, R. Poli
ACS Macro Lett., 2017, 6, 959 – 962.

Catalyzed Radical Termination in the Presence of Tellanyl Radicals
T. G. Ribelli, S. M. W. Rahaman, K. Matyjaszewski, R. Poli
Chem. Eur. J., 2017, 23, 13879 – 13882.

Influence of ligand substitution on molybdenum catalysts with tridentate Schiff base ligands for the organic solvent-free oxidation of limonene using aqueous TBHP as oxidant
W. Wang, D. Agustin, R. Poli
Mol. Cat., 2017, 443, 52 – 59.

Towards a global greener process: from solvent-less synthesis of molybdenum(VI) ONO Schiff base complexes to catalyzed olefin epoxidation under organic-solvent-free conditions
M. Cindrić, G. Pavlović, R. Katava, D. Agustin
New J. Chem., 2017, 41, 594 – 602.

Chiral bidentate [N,S]-ferrocene ligands based on a thiazoline framework. Synthesis and use in palladium-catalyzed asymmetric allylic alkylation
E. P. Sanchez-Rodriguez, F. Hochberger-Roa, R. Corona-Sanchez, J. E. Barquera-Lozada, R. A. Toscano, M. Urrutigoity, M. Gouygou, M. C. Ortega-Alfaro, J. G. Lopez-Cortes
Dalton Trans., 2017, 46, 1510 – 1519.

Sulfur in Catalysis
P. Kalck
In Applied Homogeneous Catalysis with Organometallic Compounds: A Comprehensive Handbook. B. Cornils, W. A. Herrmann, M. Beller, & R. Paciello (Eds.), (3rd edition). Weinheim: Wiley-VCH, 2017, 1557 – 1578.

P. Kalck, M. Urrutigoïty
In N-Heterocyclic Carbenes in Catalytic Organic Synthesis. S. P. Nolan, & C. S. J. Cazin (Eds.), Stuttgart: Georg Thieme Verlag KG, 2017,463 – 471.

1- η5-Oxocyclohexadienyl ligands in transition metal chemistry: Neglected (Brønsted) base ligands in cooperative catalysis
A. Igau
Coord. Chem. Rev., 2017, 344, 299 – 322.

Transition-Metal-Free Catalytic Hydrodefluorination of Polyfluoroarenes by Concerted Nucleophilic Aromatic Substitution with a Hydrosilicate
K. Kikushima, M. Grellier, M. Ohashi, S. Ogoshi
Angew. Chem. Int. Ed., 2017, 56, 16191 – 16196.

Ruthenium-Catalyzed Tandem Activation of C≡N and B-H Bonds under Dihydrogen: Synthesis of BN Heterocycles
M. Beguerie, C. Faradji, L. Vendier, S. Sabo-Etienne, G. Alcaraz
ChemCatChem, 2017, 9, 3303 – 3306.

Olefin Metathesis with Ru-Based Catalysts Exchanging the Typical N-Heterocyclic Carbenes by a Phosphine–Phosphonium Ylide
L. Arnedo, R. Chauvin, A. Poater
Catalysts, 2017, 7, 1 – 12.

Rh(III)-Catalyzed Synthesis of Multisubstituted Isoquinolines from Benzylamines and Diazo Compounds
X. Lin, R. Chauvin, Y. Yu, L. Wang, L. Xu, X. Cui
ChemistrySelect,2017, 2, 2383 – 2387.

Rh-catalyzed Regioselective ortho-CH Carbenoid Insertion of Diarylazines
Y. Yu, C. Kuai, R. Chauvin, N. Tian, S. Ma, X. Cui
J. Org. Chem.,2017, 82, 8611 – 8616.

Homogeneous Metal Catalysis: An Undergraduate Introduction
P. W. N. M. van Leeuwen In: Reedijk, J. (Ed.) Elsevier Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
Waltham, MA: Elsevier, 2017, doi:10.1016/B978-0-12-409547-2.11101-1.

Ligand effects in rhodium-catalyzed hydroformylation with bisphosphines: steric or electronic?
Y. Jiao, M. Serrano Torne, J. Gracia, J. W. Niemantsverdriet, P. W. N. M. van Leeuwen
Catal. Sci. Technol., 2017, 7, 1404 – 1414.

Azobenzene-based ruthenium(II) catalysts for light-controlled hydrogen generation
A. Telleria, P. W. N. M. van Leeuwen, Z. Freixa
Dalton Trans., 2017, 46, 3569 – 3578.

Gold(I) catalysed asymmetric hydroamination of alkenes: the unveiling of a silver and solvent dependent enantiodivergent reaction
M.-A. Abadie, X. Trivelli, F. Medina, N. Duhal, M. Kouach, B. Linden, E. Génin, M. Vandewalle, F. Capet, P. Roussel, I. Del Rosal, L. Maron, F. Agbossou-Niedercorn, C. Michon
Chem. A Eur. J., 2017, 23, 10777 – 10788.

Mechanistic Aspects of the Polymerization of Lactide Using a Highly Efficient Aluminum(III) Catalytic System
C. Robert, T. E. Schmid, V. Richard, P. Haquette, S. K. Raman, M.-N. Rager, R. M. Gauvin, Y. Morin, X. Trivelli, V. Guérineau, I. del Rosal, L. Maron, C. M. Thomas
J. Am. Chem. Soc., 2017, 139, 6217 – 6225.

Experimental and Computational Investigations on Highly Syndioselective Styrene–Ethylene Copolymerization Catalyzed by Allyl ansa-Lanthanidocene
E. Louyriac, E. Laur, A. Welle, A. Vantomme, O. Miserque, J.-M. Brusson, L. Maron, J.-F. Carpentier, E. Kirillov
Macromolecules, 2017, 50, 9577 – 9588.

Organocalcium-mediated nucleophilic alkylation of benzene
A. S. S. Wilson, M. S. Hill, M. F. Mahon, C. Dinoi, L. Maron
Science, 2017, 358, 1168 – 1171.

Reductive Disproportionation of CO2 with Bulky Divalent Samarium Complexes
M. Xémard, V. Goudy, A. Braun, M. Tricoire, M. Cordier, L. Ricard, L. Castro, E. Louyriac, C. E. Kefalidis, C. Clavaguéra, L. Maron, G. Nocton
Organometallics, 2017, 36, 4660 – 4668.

Highly Reactive Scandium Phosphinoalkylidene Complex: C–H and H–H Bonds Activation
W. Mao, L. Xiang, C. Alvarez Lamsfus, L. Maron, X. Leng, Y.Chen
J. Am. Chem. Soc., 2017, 139, 1081 – 1084.

Efficient Reduction of Carbon Dioxide to Methanol Equivalents Catalyzed by Two-Coordinate Amido–Germanium(II) and −Tin(II) Hydride Complexes
T. J. Hadlington, C. E. Kefalidis, L. Maron, C. Jones
ACS Catal., 2017, 7, 1853 – 1859.

Samarium-Catalyzed Diastereoselective Double Addition of Phenylphosphine to Imines and Mechanistic Studies by DFT Calculations
J. Li, C. A. Lamsfus, C. Song, J. Liu, G. Fan, L. Maron, C. Cui
ChemCatChem, 2017, 9, 368 – 372.

Substitution Effects in Highly Syndioselective Styrene Polymerization Catalysts Based on Single-Component Allyl ansa-Lanthanidocenes: An Experimental and Theoretical Study
E. Laur, E. Louyriac, V. Dorcet, A. Welle, A. Vantomme, O. Miserque, J.-M. Brusson∥, L. Maron, J.-F. Carpentier, E. Kirillov
Macromolecules, 2017, 50, 6539 – 6551.


Insights into the Cascade Reaction of CO and Heteroallenes Mediated by Dinitrogen Hafnocene Complexes : The Indirect Effect of Nitride’s Nucleophilicity
C. E. Kefalidis, L. Maron
Chem. Eur. J., 2016, 14, 4743 – 4747.

Mechanistic insight from theory on the reduction of CO2, N2O, and SO2 molecules using tripodal diimine-enolate substituted magnesium(I) dimers
C. E. Kefalidis, C. Jones, L. Maron
Dalton Trans., 2016, 37, 14789 – 14800.

Actinide-Catalyzed Intermolecular Addition of Alcohols to Carbodiimides
R. J. Batrice, C. E. Kefalidis, L. Maron, M. S. Eisen
J. Am. Chem. Soc., 2016, 7, 2114 – 2117.

Correlation between the Selectivity and the Structure of an Asymmetric Catalyst Built on a Chirally Amplified Supramolecular Helical Scaffold
A. Desmarchelier, X. Caumes, M. Raynal, A. Vidal-Ferran, P. W. N. M., van Leeuwen, L. Bouteiller
J. Am. Chem. Soc., 2016, 138, 4908-4916.

Boron-Mediated Activation of Carbon Dioxide
S. Bontemps
Coord. Chem. Rev., 2016, 308, Part 2, 117-130.

Direct synthesis of dicarbonyl PCP-iron hydride complexes and catalytic dehydrogenative borylation of styrene
S. Jiang, S. Quintero-Duque, T. Roisnel, V. Dorcet, M. Grellier, S. Sabo-Etienne, C. Darcel, J.-B. Sortais
Dalton Trans., 2016, 45, 11101-11108.

Functional Short-Bite Ligands: Synthesis, Coordination Chemistry, and Applications of N-Functionalized Bis(diaryl/dialkylphosphino)amine-type Ligands
C. Fliedel, A. Ghisolfi, P. Braunstein
Chem. Rev., 2016, 116, 9237-9304.

Synthesis of axially chiral biaryl compounds by asymmetric catalytic reactions with transition metals
P. Loxq, E. Manoury, R. Poli, E. Deydier, A. Labande
Coord. Chem. Rev.,
2016, 308, 131-190.

Effect of Ligand Structure on CuII-R Bond Strength and its Consequences for Catalytic Radical Termination and ATRP: An Experimental and Theoretical Study
T. G. Ribelli, S. M. W. Rahaman, K. Matyjaszewski, R. Poli
Macromolecules, 2016, 49, 7749-7757.

Oxidation of alcohols by TBHP in the presence of sub-stoichiometric amounts of MnO2
C. Bhaumik, D. Stein, S. Vincendeau, R. Poli, E. Manoury
C. R. Chim., 2016, 19, 566-570.

New chiral phosphorus-containing calixarenes: synthesis and catalytic applications
A. Karpus, O. Yesypenko, V. Boiko, R. Poli, J.-C. Daran, Z. Voitenko, V. Kalchenko, E. Manoury
Eur. J. Org. Chem., 2016, 3386–3394.

Dioxotungsten(VI) complexes with isoniazid-related hydrazones as (pre)catalysts for olefin epoxidation: solvent and ligand substituent effects
V. Vrdoljak, J. Pisk, B. Prugovečki, D. Agustin, P. Novak, D. Matković-Čalogović
RSC Adv.
, 2016, 6, 36384-36393.

OH-Substituted Tridentate ONO Schiff base ligands and related molybdenum(VI) complexes for solvent-free (ep)oxidation catalysis with TBHP as oxidant
W. Wang, J.-C. Daran, R. Poli, D. Agustin
J. Mol. Catal. A, 2016, 416, 117-126.

Cobalt(III) and copper(II) hydrides at the crossroad of catalyzed chain transfer and catalyzed radical termination: a DFT study
S. M. W. Rahaman, K. Matyjaszewski, R. Poli
Polym. Chem., 2016, 7, 1079-1087.

Chiral ferrocene-based P,S ligands for Ir-catalyzed hydrogenation of minimally functionalized olefins. Scope and limitations
M. Biosca, M. Coll, F. Lagarde, E. Bremond, L. Routaboul, E. Manoury, O. Pamies, R. Poli, M. Dieguez
Tetrahedron, 2016, 72, 2623–2631.

Carbene Metal Complexes in the Hydroaminomethylation Reaction
Ph. Kalck, M. Urrutigoïty
N-Heterocyclic Carbenes in Catalytic Organic Synthesis, Science of Synthesis, S.P. Nolan and C.S.J. Cazin Volume Editors; 2016, 5a, 463-471.

[N,P]-pyrrole PdCl2 complexes catalyzed the formation of Dibenzo-a-pyrone and lactam analogues
J. V. Suarez-Meneses, A. Oukhrib, M. Gouygou, M. Urrutigoïty, J-C. Daran, A. Cordero-Vargas, M. C. Ortega-Alfaro, J. G. López-Cortés
Dalton Trans. 2016, 45, 9621-9630.

Direct phosphonation of quinoxalin-2(1H)-ones under transition-metal-free conditions
M. Gao, Y. Li, L. Xie, R. Chauvin, X. Cui
Chem. Commun., 2016, 52, 2846-2849.

Platinum-catalysed intermolecular addition of carbonyl compounds to 1,6-enynes: Investigation of a new reaction pathway
K. Fourmy, M. El Louz, S. Mallet-Ladeira, J. C. Daran, O. Dechy-Cabaret, M. Gouygou
Dalton Trans., 2016, 45, 13294–13299.

BH3 Activation by Phosphorus-Stabilized Geminal Dianions: Synthesis of Ambiphilic Organoborane, DFT Studies, and Catalytic CO2 Reduction into Methanol Derivatives
M. Lafage, A. Pujol, N. Saffon-Merceron, N. Mézailles
ACS Catal., 2016, 6, 3030-3035.

Novel nucleophilic/basic and acidic organocatalysts for reaction between poorly reactive diisocyanate and diols
F.-Z. Belmokaddem, J. Dagonneau, J. Lhomme, R. Blanc, A. Garduño-Alva, C. Malivernay, A. Baceiredo, E. Maerten, E. Fleury, F. Mechin
Designed Monomers and Polymers, 2016, 19, 347 – 360.

Gold-catalyzed bis(stannylation) of propiolates
F. Chahdoura, N. Lassauque, D. Bourissou, A. Amgoune
Org. Chem. Front., 2016, 3, 856-860.

Silacyclopropylidene Platinium(0) Complex As Robust and Efficient Hydrosilylation Catalyst
T. Troadec, A. Prades,  R. Rodriguez, R. Mirgalet, A. Baceiredo, N. Saffon-Merceron, V. Branchadell, T. Kato
Inorg. Chem., 2016, 55, 8234 – 8240.

Ring-opening polymerization of e-caprolactone catalyzed by ionic hydrogen bond activation with bis-pyridiniums
G. Gontard, A. Amgoune, D. Bourissou
J. Polymer Sci., Part A: Polymer. Chem., 2016, 54, 3253-3256.

Synthesis and Coordination Modes of New Phosphine-Sulfoxide Ligands for Asymmetric Allylic Alkylation
I. Alvarado-Beltran, M. Lozano Gonzalez, Y. Escudié, E. Maerten,  N. Saffon-Merceron, C. Alvarez-Toledano, A. Baceiredo
Tetrahedron, 2016, 72, 1662 – 1667.

Two-coordinate terminal zinc hydride complexes : synthesis, structure and preliminary reactivity studies
M. J. C. Dawkins, E. Middleton, C. E. Kefalidis, D. Dange, M. M. Juckel, L. Maron, C. Jones
Chem. Commun., 2016, 69, 10490 – 10492.

Iridium versus Iridium: Nanocluster and Monometallic Catalysts Carrying the Same Ligand Behave Differently
I. Cano, L. M. Martinez-Prieto, B. Chaudret, P. W. N. M. van Leeuwen
J. Polymer Sci., Part A: Polymer. Chem., 2016, 54, 3253-3256.

Synthesis and Coordination Modes of New Phosphine-Sulfoxide Ligands for Asymmetric Allylic Alkylation
I. Alvarado-Beltran, M. Lozano Gonzalez, Y. Escudié, E. Maerten,  N. Saffon-Merceron, C. Alvarez-Toledano, A. Baceiredo
Tetrahedron, 2016, 72, 1662 – 1667.

A case study of proton shuttling in palladium catalysis
J. Monot, P. Brunel, C. E. Kefalidis, N. A. Espinosa-Jalapa, L. Maron, B. Martin-Vaca, D. Bourissou
Chem. Sci., 2016, 7, 2179-2187.


Hydroboration of Carbon Dioxide using Ambiphilic Phosphine-Borane Catalysts: On the Role of the Formaldehyde Adduct
R. Declercq, G. Bouhadir, D. Bourissou, M.-A Légaré, M.-A. Courtemanche, K. Nan, N. Bouchard, F.-G. Fontaine
ACS Catal., 2015, 5, 2513-2520.

Direct Ring-Opening of Lactide with Amines: Application to the Organo-catlayzed Preparation of Amide End-capped PLA and to the Removal of Residual Lactide from PLA Samples
A. Alba, O. Thillaye du Boullay, B. Martin-Vaca, D. Bourissou
Polym. Chem., 2015, 6, 989.

Metal-free intermolecular azod-alkyne cycloaddition promoted by glycerol
L. Rodriguez-Rodriguez, E. Gras, M. A. Pericàs, M. Gómez
Chem. Eur J., 2015, 21, 18706-18710.

A Highly Effective Ruthenium System for the Catalyzed Dehydrogenative Cyclization (CDC) of Amine-Boranes to Cyclic Boranes Under Mild Conditions
C. J. Wallis, G. Alcaraz, A. S. Petit, A. I. Poblador-Bahamonde, E. Clot, C. Bijani, L. Vendier, S. Sabo-Etienne
Chem., Eur. J. 2015, 21, 13080-13090.

A ruthenium dihydrogen germylene complex, and the catalytic synthesis of digermoxane
K. A. Smart, E. Mothes-Martin, L. Vendier, R. N. Perutz, M. Grellier, S. Sabo-Etienne
Organometallics, 2015, 34, 4158-4163.

Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C-N, C-O, and C-C Bonds
G. Jin, C. G. Werncke, Y. Escudié, S. Sabo-Etienne and S. Bontemps
J. Am. Chem. Soc., 2015, 137, 9563-9566

Iron-Catalyzed Reduction of CO2 into Methylene: Formation of C-N, C-O, and C-C Bonds
G. Jin, C. G. Werncke, Y. Escudié, S. Sabo-Etienne and S. Bontemps
J. Am. Chem. Soc., 2015, 137, 9563-9566.